This article is part of our Soccer Picks series.

The UEFA Champions League is back with the third matchday of the league phase. There have been some surprises in the last two weeks: Brest and Benfica have already picked up three points, while Bayern Munich, FC Barcelona and Real Madrid have already lost a game.

This is the nature of European football and further surprises are inevitable. There are plenty of top duels this week, with Tuesday taking center stage: Real Madrid, Borussia Dortmund, PSG and Arsenal.

The best UEFA Champions League bets for Borussia Dortmund at Real Madrid

Over 3.5 goals between Real Madrid and Borussia Dortmund +100

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These two European heavyweights met a few months ago in the 2023/24 UEFA Champions League final, where Los Merengues secured victory thanks to second-half goals from Dani Carvajal, who will miss this game due to a season-ending knee injury, and Vinicius Junior. Both teams look completely different in this new 2024/25 season and it wouldn’t be a surprise if it was a back and forth game with lots of goals.

Real Madrid have just picked up two consecutive wins in La Liga against Villarreal and Celta Vigo, but after losing to Lille in their last UCL game they will find it difficult to get three points in this place. The fact that they have conceded goals in their two European games does not bode well for their chances of keeping a clean sheet here, as Dortmund sit top of the UCL with 10 goals scored in just two games. Furthermore, none of Carlo Ancelotti’s 14 coaching games against BVB ended in a draw, so everything points to this game being a high-scoring affair.

The best UEFA Champions League bets for PSV Eindhoven at PSG

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Few players in Europe’s top leagues are as hot as Barcola, who has already scored seven goals and provided one assist in eight Ligue 1 appearances. Although he is yet to score in the Champions League, there is no doubt that Barcola will be looking to open his European campaign against a PSV Eindhoven defense that will find it difficult to stop the Parisiens’ fast-paced back three.

PSV are in good form this season, having won their first nine games in the Eredivisie while averaging over three goals per game. Still, it’s hard to imagine a scenario in which they would attack at full strength against PSG in Paris. The French should finally find space in the final meters and Barcola has been deadly this season. This represents as good a chance as any for him to end his goal drought in Europe.

UEFA Champions League best bets for Shakhtar Donetsk at Arsenal

Arsenal -3.5 goals against Shakhtar Donetsk +187

Arsenal desperately need a clear win, or at least an attempt at recovery, after their 2-0 defeat to Bournemouth last weekend. Defeat to the Cherries marked the end of Arsenal’s unbeaten run this season and Mikel Arteta’s men have a golden chance to get back to winning ways at home when they host Shakhtar Donetsk.

The Ukrainian team may have picked up a win in their last home game, but they have struggled in Europe this season after going winless in their first two UCL games, failing to score on both occasions. Don’t expect that to change as there are big differences between Arsenal and Shakhtar in terms of talent.

That should be noticeable in this game and the Gunners should have no problems winning by a big margin. Arsenal have won by at least two goals in five of their six games at the Emirates Stadium in the 2024/25 season in all competitions and should take advantage of a tired Shakhtar side to record one of their biggest wins of the season.

UEFA Champions League best bets for Slovan Bratislava in Girona

Both teams score a “Yes” -106 between Girona and Slovan Bratislava

On the surface, Girona are the better team before this game, and that’s not even close to the case. However, the Spanish club is going through a serious injury phase and will be without several regular players in this game. This situation has led manager Michel to adjust his tactical approach due to a lack of depth, particularly in the final third. They shouldn’t have much trouble getting the three points against Slovan Bratislava, but it won’t be a walk in the park for the Catalan team.

Despite losing his first two Champions League games 9-1 on aggregate, Slovan scored in the defeat to Celtic before being brutally outclassed by Manchester City. Given Girona’s injury situation, it wouldn’t be surprising if Slovan were able to score in this game, even if they end up losing and falling further behind in the UCL standings. Expect both teams to find the net at the Estadio Municipal de Montilivi.

Champions League betting tips Tuesday October 22nd

• Over 3.5 goals between Real Madrid and Borussia Dortmund +100
• Bradley Barcola scores +160 at any time for PSG
• Arsenal wins by at least three goals against Shakhtar +187
• Both teams score a “Yes” -106 between Girona and Slovan Bratislava

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